https://nova.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:47171 in-situ Fe-oxide precipitation process modified the active surface sites of the imogolite. The Fe–oxide, mainly magnetite, favored the contaminants’ adsorption over the pristine imogolite. The adsorption kinetics of these pollutants were adequately described by the pseudo-second order and intraparticle diffusion models. The kinetic models showed that surface adsorption was more important than intraparticle diffusion in the removal of the pollutants by all the adsorbents. The Langmuir-Freundlich model described the experimental adsorption data, and both nanocomposites showed greater adsorption capacity than the imogolite. The adsorption of Cu and Cd was sensitive to cationic competition, showing a decrease of the adsorption capacity when the two cations coexisted, while their adsorption increased in the presence of arsenate.]]> Wed 14 Dec 2022 15:49:11 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:37953 VI and As^V from water in mono- and binary-adsorbate systems. The adsorption kinetics and isotherm data for Se^VI and As^V were adequately described by the pseudo-second-order (PSO) (r²>0.94) and Freundlich (r²>0.93) equations. Results from scanning electron microscopy showed that the dimension of the NZVI immobilized on the Mt was smaller than pure NZVI. Using 0.05 g of adsorbent and an initial 200 mg L⁻¹ As^V and Se^VI concentration, the maximum adsorption capacity (q_max and partition coefficient (PC) for As^V on NZVI-Mt in monocomponent system were 54.75 mg g^-1 and 0.065 mg g^-1·μM^-1, which dropped respectively to 49.91 mg g^-1 and 0.055 mg g^-1·μM^-1 under competitive system. For Se^VI adsorption on NZVI-Mt in monocomponent system, q_max and PC were 28.63 mg g^-1 and 0.024 mg g^-1·μM^-1, respectively. Values of q_max and PC were higher for NZVI-Mt than NZVI and montmorillonite, indicating that the nanocomposite contained greater adsorption sites for removing both oxyanions, but with a marked preference for As^V. Future research should evaluate the effect of different operational variables on the removal efficiency of both oxyanions by NZVI-Mt.]]> Wed 06 Dec 2023 09:51:50 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:34738 0.96). The As(V) removal capacity was higher using Z-nZVI than nZVI both in the single and multi-component systems, suffering minimal differences in removal in both cases. The results suggested that Z-nZVI had more specific surface sites for As(V) than nZVI and zeolite, which makes Z-nZVI a more effective adsorbent than nZVI for the removal of As(V) from aqueous solutions in the presence of other oxyanions.]]> Mon 15 May 2023 10:14:02 AEST ]]>